With a temp of 23C you wouldn't think heat stress would show up but that's sure what it looks like. What is your humidity like? A really low RH causes it's own problems and that's what I've been dealing with for 20 years here up north.
I'm thinking it could be radiant energy from your LED light causing the leaf temp to get too high but moving the light back should show improvement if that were the case. When I'm playing around with setting up my HID light(s) I use an infrared laser thermometer to check the leaf temps. Much more accurate than the old back of the hand method.
I've never seen a pH problem cause leaf edge curl before. When pH gets too high it can lock out micro-nutrients and then you see shit happen to newer growth like twisting, yellowing etc. Almost all the micro-nutrients are immobile so the plant can't steal them from older leaves like it can with the mobile nutes that are N,P,K, Mg and Zn.