This is why I’m a big fan of what you and LED Teknik do for us, massive detail laid out in a way we can understand. Before the 420 boards I was planning a complicated custom build of different Led’s to achieve something like the 420 boards, it would have been more costly and time consuming although more flexibility. I spoke with LED Teknik about 430nm and at that time the most efficient way seemed to be the pc blue. I probably overthink a lot of stuff to be honest, so if you say there’s enough 430nm I should listen lol. Are the pc blue buddies still in the pipeline? I understand there’s been a lot of problems for LED Teknik but wasn’t sure if that’s a delay or cancellation?
Yes, Blue Buddies are on their way but supply chains post-Covid etc have delayed a lot of things. We've been working on the High Light strips for a long time now but things have just been slow.
430nm is an interesting wavelength because as you can see from the absorption chart above it is captured by both Chlorophyll A and B. But before I continue I need to point out that there is no real consensus on these types of charts as you can look at different sources that place the absorption peaks at different levels because of the way they measure it. Early tests used diethyl ethyl as a solvent to dissolve chlorophyll but it has been pointed out that plants are made up of water not solvents so there have been other tests using acetone and water and both had different results.
It is hard to quote actual numbers because of all the different sources but it seems to be generally accepted that peak absorption of Chlorophyll A is around 430nm and 660nm and Chlorophyl B is 450nm and 640nm. There is 3-4x as much Chlorophyll A as B, but this can change depending on the light source. In weaker light and in shade plant species there is more Chlorophyll B, so the ratio can be as low as 2x A to B. Interestingly the Max Planck Institute has published research claiming "true" Chlorophyll A peak absorption is at 372nm and 642nm and Chlorophyl B is at 392nm and 626nm, which is much bluer than traditionally thought.
Caratenoids are often overlooked, but they also help capture light for photosynthesis and they seem to favour the cyan range around 470nm. To confuse things even more, Chlorophylls C and D absorb outside the PAR range (400-700nm) and into the Far Red range as well as the blue and UV ranges.
Here is yet another chart from another source that is quite interesting.
https://www.rseco.org/content/122-chlorophyll-absorption-and-photosynthetic-action-spectra.html
It really depends on which charts you believe but we do know that plants adapt to whatever light is available and we do know that the blue and red ends of the spectrum are most efficient. Traditionally Chlorophyll A was targeted at 430nm and 660nm and Chlorophyll B at 450nm and 640nm. Current LED technology means it is most efficient to target Chlorophyll A at 660nm and Chlorophyll B at 450nm. We do the same but have hedged our bets by producing a very broad Red and Blue spectrum as well as adding a large amount of Far Red light, which we know from research works very well.
What all this means is that we have to measure LED efficiency against photosynthetic efficiency. We can produce 660nm red light very efficiently using monochromatic 3535s. And we can produce 450nm very efficiently using white phosphor 3030s. But outside those two peaks other wavelengths require more energy. We can boost the red range using narrow band phosphor technology, which we do.
We have 430nm and 470nm mono LEDs that could be used to fill in the 430 and 470 (cyan) gaps, but neither of those LEDs is very efficient. We can boost cyan using certain white phosphor LEDs (Vitasolis), which we do, so then it boils down to what else do we target? We knew that the original High Light 420 spectrum worked so well because we had the Red end of the spectrum so well covered, including Far Red, with a complete balance of Blue light all the way down to 400nm.
So we looked outside photosynthesis at photomorphogenesis because when you target flowering plants it's not just about photosynthesis but flowering structure, development and production of secondary metabolites such as cannabinoids. For that we decided to bump the UV and include a highly efficient 405nm diode (72% efficient Nichia 3535) that covered the UV range but also spilled over into the 420-430nm range. What we ended up with was a Gen2 spectrum that was very similar to the original High Light 420 spectrum but with more UV, a little bit more Far Red and about the same amount of 430nm. We basically just swapped out a 660 for 405 and boosted the rest of the range with a blend of different Nichia and narrow band phosphor LEDs.