hello....
I like flat white on everything in my room even the inside of the hoods, walls tables.etc etc .... flat white has a more even dispersion of light than mylar ...mylar has a slightly higher reflectivity but has hot spots ...like shining sun through a magnifying lens .... flat white on everything... cheap and works great... i have to wear uv sunglasses in my room its so bright..
i dont think any change of reflectivity will help your temp issue... all the above post are correct concerning ventilation .. get a good fan i use 4 vortex fans pulling fresh air into my rooms and i stay around 75ish...and i run several 1000 hps and two 8 bulb t5 sets over babies
a six inch vortex will vent that sucker out ...to the tune of 449 cubic feet of air per minute...
temp issues are a major factor in any grow...
depending on the weather in your area a really good fan will do the trick.. if not get inventive with air conditioning and duct work from homedepot
dont try to save money on cheap fans get a good one your yield will pay for the fan first crop many times over... if security is an issue mount the fans on rubber and use insolation around the ducts to cut down vibration and noise..
good luck