From what I have determined, unless you want stretchier plants, you want to use red light throughout the process. An excess of red light will also transition your plant into flowering faster. You only want a small amount of blue light, less than 10%, if you want very short bushy plants.
Here's a study explaining the effect of red light and plants:
http://flor.hrt.msu.edu/assets/Uploads/Red-light3.pdf
From the publication: Many plants grown under only red light, such as plants grown indoors under only red LEDs, have a stretched, elongated appearance; the leaves are thin and large and plants become tall. In most cases, plants grown under only red light do not have desirable growth characteristics. However, when a relatively small amount of blue light is added to red light, extension growth of plants is inhibited. Therefore, plants grown indoors with 80 to 90 percent red light and 10 to 20 percent blue light are quite compact, with smaller leaves and shorter stems.
Here's a more extensive study into why that is:
https://digitalcommons.usu.edu/cgi/viewcontent.cgi?article=5650&context=etd
Interesting conclusions:
At a PPF of 500, increasing blue light from 11 to 28 % decreased dry mass in tomato, cucumber, radish, and pepper, but there was no significant effect on soybean, lettuce and wheat. At a PPF of 200, dry mass significantly decreased only in tomato across the blue light range. Effects on leaf area paralleled effects on dry mass in all species at both PPFs, indicating that the effects of blue light on dry mass were mediated by changes in leaf area
Also note: The 3500k spectrum / HPS seems to be the best producer according to the study data. Probably due to it's excess in the red spectrum and it's super high intensity.