Lime is alkaline. Dolomite can be a different story.
Agricultural lime is used to RAISE the pH of soil.. it is used to LOWER the acidity of soil. That means it's alkaline or at the very least a pH over 7. I think some folks are misreading those statements when they read the facts, and think it raises the acidity.
Slaked or hydrated lime will raise the pH the most and quickest. It contains a high level of Calcium hydroxide. Other forms of lime contain mostly calcium carbonates with some calcium hydroxide and calcium oxide.
JRod,.. I'm sure you did put some dolomite in a glass with some water and stuck a pH meter in it and measured 7. The fact that it reduced pH in your case is incidental and I can't imagine that it would normally be used for that because it's not good at it. It's much easier to use a few drops of citric acid or lemon juice.
But tap water is not buffered at all, whatever was in your dolomite reduced the pH. Tap water pH is high usually only for one reason and that is high levels of alkalinity. Some municipalities add it to prevent corrosion. Dolomite is carbonate based,.. which is alkalinity, which is part of the reason why your tap pH is high. Adding carbonate to lower pH doesn't make sense, unless it's over 8.4 coming out of the tap. Even in that scenario.,. carbonates are so insoluble I'm not sure you'd see much of an effect from carbonate alone. It dissolves more in acidic solutions to make carbon dioxide and water.
Dolomite is called that because it contains magnesium carbonate as well as calcium carbonate, but since it's collected from mines,.. and not processed much, it has a variety of constituents, and isn't entirely consistent from mine to mine and some can have higher levels of sulfates and lower levels of bicarbonates. BUT even carbonates, which dolomite is, buffers pH to about 8,.. if you let it dissolve enough,.. bicarbonates buffer to around 8.4 (if I remember right) and hydroxides go to 14. The magnesium or calcium have no affect on pH.
pH is a direct measure of hydrogen ion concentration or H+ It is the inverse log of the hydrogen ion concentration. that means each unit you go,.. is a log change in concentration.
Things that react with H+ are carbonates which if allowed to dissolute,.. will make carbon dioxide and react with the H to make water. Carbonate = CO3 so if allowed to dissolve> CO3 + 2H = CO2 + H20
bicarbonates pretty much do the same thing,. only they're HCO3 and they make CO2 and hydroxides.
Carbonate chemistry and pH isn't easy to understand and I'm no expert,. But when "looking it up" I can't find a site that isn't a stoner forum,.. that says use carbonates to reduce pH.
Oxides are virtually insoluble.
Carbonates are hardly soluble,.. I mean you're lucky to get a couple hundred ppm,.. and buffer to pH 8.
Bicarbonates are relatively soluble and buffer to pH 8.4ish.
Hydroxides are very soluble and since they react directly with the H+'s and very rapidly, the pH is basically limited to the solubility of the material.