This is a young plant in a deep water culture under a 250 watt hps light is a closet with great air flow. I have 3 other young plants that do not have this problem which is only on the lower leaves. any suggestions? thanks.
6.5 is a little high for dwc. Around 5.8 is optimal, but that doesn't look like your problem. I think your nutes are a bit to strong, the burning on the edge of the leaves looks like nute burn, but I'm not very good at addressing hydro problems so I could be wrong.
I guess a question i should have asked earlier, is are they all in same res or diff 1s? If they're are n the same, i would lower ph, and water temp. Then give it a cpl dys, if it doesnt get better or starts getting worse then lower your ppms.
What nutes are you running
Try lowering ppm, ph and water temp see how she does.
I put frozen gal jugs of water in my res every day to keep temps cool, but i'm running 50 gal res with flood and drain. For yours you could add a frozen 20oz bottle. I ended up switching my dwc res to an old cooler and it works great. Keeps the water temps steady and even has a drain plug to drain for res changes.
6.0 is too high and now 5.8 would be too high since potassium is a tricky nutrient you may want to lower it to 5.5 cause it does look like you getting K def.