Calcium Carbonate & CaCO3

kratos015

Well-Known Member
I don't even consider purple stems anymore as long as the leaves are healthy and growth is good. My tap is 140 ppm with about 50 ppm of calcium and I always feed my tomatoes outside just fish emulsion, and occasionally supplement epsom salts. I never add calcium and my calcium levels always test out as normal-high and I never get blossom end rot. Some of the calcium in tap water is definitely being used. I did away with calmag inside and just stick with epsom salts for additional mag. Kratos is right, those municipal water test reports are goldmines of information.
Same here friend. You been growing tomatoes for long? I only just started growing produce, so I'd very much like to have someone's brain to pick concerning that. In an outside setting of course, don't want to hijack OPs thread.


As you and others have pointed out, red/purple petioles are sometimes genetic, and by themselves aren't sufficient enough to claim P deficiencies/lockout. If one's leaves have the bluish/purplish hues to them, then you can know for certain there's a problem with P. It is crucial at this point to ensure the lack of P is not from a lockout, as people tend to feed with more P instead of finding out why there is a lockout in the first place.

I never experienced End Rot, but the bulk of my struggles have been with fruits not setting. When I apply Langbeinite, fruits set and produce just fine, problem solved. Apparently, a combination of the intense irrigation required to grow in Arizona, as well as the dry-arid climate of my region, native dirt high in Clay/Sand, and excess Ca in my water, tends to result in both K and Mg being leeched from my soil into literal thin air.

I've been experimenting quite a bit with Langbeinite as a result of what I described above, and observing how it reacts with the large amounts of CaCO3 in my water.

Calcium, Magnesium, and Potassium make up a "trinity" so to speak, as some of you have seen me reference before, right? So my theory was, if the three are intertwined with one another, and I have loads of Calcium in my water (and soil, by proxy) then the excess Ca will work in tandem with the high levels of Mg and K found in Langbeinite. My thinking is that the Ca:Mg:K ratios should be 1:1:1, but if we look at the majority of soil recipes, we see this 1:1:1 ratio is not being adhered to. Furthermore, we see a discrepancy with what people believe the "proper" Ca:Mg ratios should be (while they ignore K). Some say Ca:Mg ratios should be 5:1, others will tell you 20:1, and lastly others will tell you that Ca:Mg ratios are bullshit (I fall into this category).

I apply Langbeinite every 2-4 weeks, depending on the size of the plant. I always apply it when I see the light green leaves synonymous with Mg deficiencies (that are often confused with N deficiency). Problem gets corrected immediately. Top dressing with Langbeinite has allowed me to forgo my Epsom Salt foliar entirely!


This is going to be a book; however, this book is the result of research I've been doing on CaCO3, Langbeinite, and Ca/Mg/K levels. Also please note, this is for MY environment, and MY soil, and MY genetics. Anyone reading this? Your variables will be different from mine. Please take that into account, and react accordingly!



As I said above, my hypothesis was that the high levels of Mg and K found in Langbeinite would work in tandem with the high levels of Ca/CaCO3 found in my water, creating a 1:1:1 ratio of Ca, Mg, and K. The experiment has been quite successful. No more fruit set failures, no more Mg deficiencies, no more issues.

Furthermore, we often see that elemental sulfur dissolves CaCO3, once the Sulfur (S) is oxidized and converted to sulfates (SO4). The advice is to use elemental sulfur, and wait for it to decompose into sulfate (SO4). But Langbeinite and even epsom salts are made with SO4 specifically.

So, why are we waiting months for Elemental Sulfur to turn into SO4 when its already found in Langbeinite and even Epsom Salts?

Epsom Salts = MgSO4
Langbeinite = K2Mg2(SO4)3

As you can see, both of the above have Sulfate (SO4) in it, so why are we told to wait for Elemental Sulfur to oxidize into SO4 when SO4 is readily available in both of the above?

Check out "this article" here. Here are some quotes and excerpts.

"The oxidation of S° to SO4 in soil is a biological process and is carried out by several kinds of micro-organisms."

As I've said and emphasized on many instances, my water is a buffer, and my water has a pH of 8.0-8.5 pH.

Problem I have is, I have fucktons of mushrooms growing in my raised beds. Mushrooms do best in 5.5-6.5 pH, so how is it that I have mushrooms growing if my water is making my water's pH alkaline?

Shrooms grow in 5.5-6.5 pH, yet I see them despite my water now. How is this possible?


The langbeinite; more specifically, the SO4 content of the Langbeinite is reacting with the CaCO3, and dissolving the CaCO3 into its separate molecules. CaCO3 is a salt, right? As we all know, salts can be dissolved in the right circumstances.

As I said above, my hypothesis was that the high levels of Mg and K found in Langbeinite would work in tandem with the high levels of Ca/CaCO3 found in my water. The experiment has been quite successful. No more fruit set failures, no more Mg deficiencies, no more issues.


But as we can clearly see above, sulfur is available in oxidized form (SO4) in both Langbeinite and Epsom salts!


As for why Coots didn't emphasize Langbeinite? Simple! He's from Oregon! His native dirt is drastically different from my native dirt that consists of sand and clay. Native dirt located in Oregon is more likely to be heavy in compost and low in clay/sand (correct me if I'm wrong), where as in the desert where I'm at, my soil is high in clay/sand but low in compost.

His water source also isn't from a well like mine is (as far as I know, I could be wrong), so of course I need to omit Ca inputs from my soil! Coots water doesn't have the Ca content that mine does, so I need to account for it! I have high levels of both Ca and CaCO3 specifically in my water, if it is in my water, it will be in my soil!

What have I found from my "experiment"? Well, as pointed out earlier, my pH is now acidic enough to facilitate mushroom growth. This mushroom growth only happened after I applied Langbeinite as a top dress. So, the only thing that explains this for me is that the SO4 in the Langbeinite dissolved some of the CaCO3 in my water and/or soil. As a result of this, the pH of my soil lowered from the standard 7.0 pH to 6.0-6.5 pH.

A pH below 7.0 should not be possible with the amount of CaCO3 I have in my water, yet the Langbeinite (More specifically, the SO4 content in it) is dissolving enough of the CaCO3 in my water to result in my soil having a 6.0-.7.0 pH!


Astonishing!

Now? I don't have as many fruits failing to set! Pretty much all of my flowers turn into fruits now. In fact, when flowers start falling off, that is the same as seeing light green leaves on my cannabis plants! Light green leaves on weed plants, just like the inability for flowers to "set", is directly related to Mg and K.

Thing about my soil? Plenty of Mg and K. My environment, and watering habits (due to Arizona weather) is literally sucking and leeching Mg and K from my soil! I need to account for that.

Again, and I heavily emphasize, I'm not posting this because it will help everyone. But I know for a fact it will help someone.
 

kratos015

Well-Known Member
Always awesome to read your posts man. Oh, but he's a she, lol.

I've become a fan of Langeinite too. I think citric acid can help a little too with high Ca. I don't know, but I've got Ca in my well water and your posts have helped a lot with it.
You the man!

I've never experimented with, nor used citric acid in a growing environment, so until you pointed out it was something that helped you, I'd have never even realized it was something that could help in the first place!

Where do you source your Citric acid from? My biggest concern would be the sustainability of the Citric Acid. Not because I'm trying to virtue signal because I'm "concerned about sustainability". I'll be straight and admit my concerns with "sustainability" are purely selfish; if the world goes to shit and I can't buy anything, can I produce it by myself at home?

Only flaw I can see with the Citric Acid is that its more of a band-aid than an actual solution, unless I'm mistaken? Don't you need to re-use the Citric Acid over and over in order for your pH to be proper? Again (and I heavily emphasize, I'm not trying to be a dick here), this is more for treating the symptoms but not treating the actual problem, yes?

I highly envy people that have citrus trees in their yard. Because if they do, they have plenty of Citric Acid freely at their disposal! Not to mention the implications for cooking. I'd kill to have a fruiting lemon tree in my yard. Literally kill.

Like I've always said, what is "perfect" for one person is disastrous for another person. Only we as growers can know what works for us, because it will depend on genetics used, as well as environmental factors, and soil quality.

Whatever works, go for it! Just make sure its self-sufficient, and that "whatever works" is something that will continue to work even if store shelves are empty.



Biggest takeaway here is that not all Calcium is in Carbonate form (i.e. Gypsum), but all CaCO3 has Ca in it. Even more interesting, excess CaCO3 causes issues related with alkaline pH.
Alkaline pH issues will be very similar to Calcium toxicity issues.

The nutrient lockouts are very similar, making the issue even more of a pain in the ass to troubleshoot, because is it excess Ca? Or is it excess CaCO3? If it is excess CaCO3, is my problem related to alkaline pH, or excessive Ca? Or both?

Why I ask so many questions; only way to troubleshoot it properly.

All the best Warrior! :)
 

PadawanWarrior

Well-Known Member
You the man!

I've never experimented with, nor used citric acid in a growing environment, so until you pointed out it was something that helped you, I'd have never even realized it was something that could help in the first place!

Where do you source your Citric acid from? My biggest concern would be the sustainability of the Citric Acid. Not because I'm trying to virtue signal because I'm "concerned about sustainability". I'll be straight and admit my concerns with "sustainability" are purely selfish; if the world goes to shit and I can't buy anything, can I produce it by myself at home?

Only flaw I can see with the Citric Acid is that its more of a band-aid than an actual solution, unless I'm mistaken? Don't you need to re-use the Citric Acid over and over in order for your pH to be proper? Again (and I heavily emphasize, I'm not trying to be a dick here), this is more for treating the symptoms but not treating the actual problem, yes?

I highly envy people that have citrus trees in their yard. Because if they do, they have plenty of Citric Acid freely at their disposal! Not to mention the implications for cooking. I'd kill to have a fruiting lemon tree in my yard. Literally kill.

Like I've always said, what is "perfect" for one person is disastrous for another person. Only we as growers can know what works for us, because it will depend on genetics used, as well as environmental factors, and soil quality.

Whatever works, go for it! Just make sure its self-sufficient, and that "whatever works" is something that will continue to work even if store shelves are empty.



Biggest takeaway here is that not all Calcium is in Carbonate form (i.e. Gypsum), but all CaCO3 has Ca in it. Even more interesting, excess CaCO3 causes issues related with alkaline pH.
Alkaline pH issues will be very similar to Calcium toxicity issues.

The nutrient lockouts are very similar, making the issue even more of a pain in the ass to troubleshoot, because is it excess Ca? Or is it excess CaCO3? If it is excess CaCO3, is my problem related to alkaline pH, or excessive Ca? Or both?

Why I ask so many questions; only way to troubleshoot it properly.

All the best Warrior! :)
You can get a lifetime supply for cheap. I bought a 5# bag and it'll last awhile. It's also awesome for removing Ca deposits and shit from taps or shower heads, dishwashers, ect. It can also be used as a foliar bug killer spray. Oh, and sour gummies and some regular gummy recipes.


It can also be bought in some grocery stores in the canning section, but it's way more expensive like that.

It's actually a little more than a bandaid. It's a chelating agent too. Citric, (probably any type of acid, I don't know) binds with the Ca so it can be flushed out. It also supposedly makes all the nutes more accessible. But even just using a little in my water helps even if I'm not gonna flush any shit out. I try not to flush anything out. I know you know what I'm talking about. But 95% of the time I only give straight 7.8 well water.

Now stop being a dick, lol.
 

kratos015

Well-Known Member
You can get a lifetime supply for cheap. I bought a 5# bag and it'll last awhile. It's also awesome for removing Ca deposits and shit from taps or shower heads, dishwashers, ect. It can also be used as a foliar bug killer spray. Oh, and sour gummies and some regular gummy recipes.


It can also be bought in some grocery stores in the canning section, but it's way more expensive like that.

It's actually a little more than a bandaid. It's a chelating agent too. Citric, (probably any type of acid, I don't know) binds with the Ca so it can be flushed out. It also supposedly makes all the nutes more accessible. But even just using a little in my water helps even if I'm not gonna flush any shit out. I try not to flush anything out. I know you know what I'm talking about. But 95% of the time I only give straight 7.8 well water.

Now stop being a dick, lol.
Thank you for educating me on it. Had no idea Citric Acid went such a long way, why I asked in the first place. If I'm not mistaken, one can make their own citric acid from pretty much any citrus plant source, no? So, anyone with citrus trees should be able to make their own citric acid? Or am I mistaken?

Not that I need more of a reason to grow citrus trees, but that is definitely one of them! Assuming I can make my own, that is ;p

Citric acid is typically what is used to make things "sour" in recipes, no? Or am I mistaken?

Realistically speaking, its more likely that I can "self sustain" my own source of citric acid, more than I can source my own Langbeinite.

As I was pointing out above, it isn't about making anyone feel shitty, it is about learning.


The only scenario I can see myself not learning is if i am dead. Or ignorant.
 

Bukvičák

Well-Known Member
Availability of calcium for your plants in your tap is closely connected with your fertilizer program. Fertilizers turn some of the calcium bonded in carbonates into form, which can be uptaken by the plant. I am not sure if the word “chelating” is the correct term, but it might work on that princip. I would not reccomend anybody to mess up with lime especially with bagged potting soil unless you are trully building your own soil.
 

lakesidegrower

Well-Known Member
@PadawanWarrior beat me to it lol
@kratos015 had been a godsend for me and my Ca issues. Have been following his(your) advice for over a year now, see these same Ca-related issues playing out to a ‘t’ in my grow as well, and much the same, it took me a while to figure that out, far less time than it would have taken however had it not been for kratos’ advice.

I think a really key piece here is that kratos pointed out above that the excess CaCO3 can cause both antagonism of Mg, K and P, as well as pH issues and that both of those issues, while related to CaCO3 content in the soil, can be mutual exclusive from each other in they way they affect the soil biology.

My well water is about 240ppm and right around a pH of 8, I have yet to get an analysis done (which no doubt will be tell tale and insightful), but I know it contains a good amount of CaCO3 given the scaling I see in my pots and on my faucets, etc. I also ran through the peat and pH tests suggested by kratos to see if my water will act as a buffer and it does not, yet I still deal with the issues we are discussing here. This caused a dissonance for me and had me doubting whether it was in fact my water (and it’s Ca content) that was causing the issues. I purchased a quality soil pH pen and found my soil pH to be above 7.5; I then presumed that Ca was responsible for the high pH in and of itself, and began to drop pH of my water with citric acid to around 5.8 with each watering. I did see the soil pH start to get into a range I wanted (between 6.5 and 7), I was happy with this but it didn’t solve the issues/deficiencies that I was dealing with. So back to the drawing board - this is what brought me back to re-reading what kratos had to say about the topic, and then it dawned on me that I wasn’t dealing with a ‘lock out’ (which really only describes a low-pH situation where nutrients can’t be absorbed) but rather I was experiencing significant antagonistic effects of a build-up of CaCO3, so I spent time with the Mulder chart - sure enough it was clear pretty quickly that the excess CaCO3 is likely my culprit due to its antagonizing effect on Mg, K and P, and that it was not simply a ‘pH issue’ in my soil. So my water, while it does not contain enough CaCO3 to act as a buffer, was still giving me CaCO3 issues after it was allowed to build up in my pots.

I should point out that over a year ago, thanks to advice from kratos, I limited my Ca inputs in my soil build - arguably I should have left them out completely. I have no issues during veg, but the two cycles I have ran in this soil have both shown the same Ca-related deficiencies in about week 2 of flower, getting progressively worse curing the cycle.

Now with all this being said, the true test will be how my next run goes as I apply my hypothesis above. I’m planning on flushing my pots, then using RO water for whole next run, I’d love to see a true Ca deficiency lol.

Hardly anyone takes the time to write such detailed responses based on both experience and education, but kratos is THE exception - Id surely be as lost as I was over a year ago without his help and insight. A true expert on the topic!
 

JimmyJackCorn

Well-Known Member
Availability of calcium for your plants in your tap is closely connected with your fertilizer program. Fertilizers turn some of the calcium bonded in carbonates into form, which can be uptaken by the plant. I am not sure if the word “chelating” is the correct term, but it might work on that princip. I would not reccomend anybody to mess up with lime especially with bagged potting soil unless you are trully building your own soil.
Between Kratos, other informative threads like this one, and my own research/experience, I am coming into the mindset where I plan to not amend my soil with any mineral/nutrient inputs.

In building my own vermicompost (technically a big pile of soil) with native regolith, leaf mold, grass clippings, kitchen vegetable waste, and garden waste, the only items I will be adding to my next soil mix with this base are mycos, aeration, and something inert to cut the strength of said compost. I am very curious to know how that will work for cannabis, and plan to mix this soil up soon so I can start testing!
 

lakesidegrower

Well-Known Member
I should also add that I think more people deal with this range of possible Ca I related issues than we hear, it just shows up in the boards as a deficiency that someone is trying to diagnose and they don’t get the results they expect when they treat it as such and add more of what they think they don’t have enough of when in fact there is likely already plenty but Ca is getting in the way, they understandably get discouraged and give up on organics and we. Hopefully I can speak from a position of a direct experience with success in dealing with it in a few months.
 

Bukvičák

Well-Known Member
I have not realized this thread is in organic section, my point was adding dry salts together with some pH adjuster will result in “releasing” calcium from carbonates partialy… This most likely not taking place in fully organic grow where synthetic nutes are not used. When it comes to my unexperienced opinion on calcium as an organic source than oyster shells are probably the way to go. Lime has breakdown about two years so I do not see any benefit except its pH adjusting ability, but again we are organic where pH should not be the concern. Organic grow is not my cup of coffee so might be wrong about that calcium sources, but with tap water grow most of us and high carbonates content is definitely an issue.
 

Week4@inCharge

Well-Known Member
I have not realized this thread is in organic section, my point was adding dry salts together with some pH adjuster will result in “releasing” calcium from carbonates partialy… This most likely not taking place in fully organic grow where synthetic nutes are not used. When it comes to my unexperienced opinion on calcium as an organic source than oyster shells are probably the way to go. Lime has breakdown about two years so I do not see any benefit except its pH adjusting ability, but again we are organic where pH should not be the concern. Organic grow is not my cup of coffee so might be wrong about that calcium sources, but with tap water grow most of us and high carbonates content is definitely an issue.
Good point, my last grow was Synthetic, this round is organic, so nervous and excited at the same time. Lots of valid points made here and I'm almost 100% sure what Calcium and Magnesium deficiencies look like now. I packed in the amendments and don't think I should see any of them though four or five weeks into a grow. With my current grow the leaves are a little darker than I'm used to and wondering if I should hold off flipping for a week or two. As I'd be adding more amendments to The topsoil next week. (per Earth Dust instructions) #Firstworldproblems
 

PadawanWarrior

Well-Known Member
Thank you for educating me on it. Had no idea Citric Acid went such a long way, why I asked in the first place. If I'm not mistaken, one can make their own citric acid from pretty much any citrus plant source, no? So, anyone with citrus trees should be able to make their own citric acid? Or am I mistaken?

Not that I need more of a reason to grow citrus trees, but that is definitely one of them! Assuming I can make my own, that is ;p

Citric acid is typically what is used to make things "sour" in recipes, no? Or am I mistaken?

Realistically speaking, its more likely that I can "self sustain" my own source of citric acid, more than I can source my own Langbeinite.

As I was pointing out above, it isn't about making anyone feel shitty, it is about learning.


The only scenario I can see myself not learning is if i am dead. Or ignorant.
Oh ya, I'm sure you could grow your own citrus trees. But it's really cheap already.

Ya, citric makes things sour. You can use it to coat gummies to make them sour gummies. But what's even better is to just use flavored Kool-Aid, because it's basically flavored citric acid, and mix in some sugar.

And I was just teasing you. I love reading your posts.
 

PadawanWarrior

Well-Known Member
@PadawanWarrior beat me to it lol
@kratos015 had been a godsend for me and my Ca issues. Have been following his(your) advice for over a year now, see these same Ca-related issues playing out to a ‘t’ in my grow as well, and much the same, it took me a while to figure that out, far less time than it would have taken however had it not been for kratos’ advice.

I think a really key piece here is that kratos pointed out above that the excess CaCO3 can cause both antagonism of Mg, K and P, as well as pH issues and that both of those issues, while related to CaCO3 content in the soil, can be mutual exclusive from each other in they way they affect the soil biology.

My well water is about 240ppm and right around a pH of 8, I have yet to get an analysis done (which no doubt will be tell tale and insightful), but I know it contains a good amount of CaCO3 given the scaling I see in my pots and on my faucets, etc. I also ran through the peat and pH tests suggested by kratos to see if my water will act as a buffer and it does not, yet I still deal with the issues we are discussing here. This caused a dissonance for me and had me doubting whether it was in fact my water (and it’s Ca content) that was causing the issues. I purchased a quality soil pH pen and found my soil pH to be above 7.5; I then presumed that Ca was responsible for the high pH in and of itself, and began to drop pH of my water with citric acid to around 5.8 with each watering. I did see the soil pH start to get into a range I wanted (between 6.5 and 7), I was happy with this but it didn’t solve the issues/deficiencies that I was dealing with. So back to the drawing board - this is what brought me back to re-reading what kratos had to say about the topic, and then it dawned on me that I wasn’t dealing with a ‘lock out’ (which really only describes a low-pH situation where nutrients can’t be absorbed) but rather I was experiencing significant antagonistic effects of a build-up of CaCO3, so I spent time with the Mulder chart - sure enough it was clear pretty quickly that the excess CaCO3 is likely my culprit due to its antagonizing effect on Mg, K and P, and that it was not simply a ‘pH issue’ in my soil. So my water, while it does not contain enough CaCO3 to act as a buffer, was still giving me CaCO3 issues after it was allowed to build up in my pots.

I should point out that over a year ago, thanks to advice from kratos, I limited my Ca inputs in my soil build - arguably I should have left them out completely. I have no issues during veg, but the two cycles I have ran in this soil have both shown the same Ca-related deficiencies in about week 2 of flower, getting progressively worse curing the cycle.

Now with all this being said, the true test will be how my next run goes as I apply my hypothesis above. I’m planning on flushing my pots, then using RO water for whole next run, I’d love to see a true Ca deficiency lol.

Hardly anyone takes the time to write such detailed responses based on both experience and education, but kratos is THE exception - Id surely be as lost as I was over a year ago without his help and insight. A true expert on the topic!
He also reminded me that breaking down posts into more readable text is helpful to the reader, lol.
 

Week4@inCharge

Well-Known Member
Oh ya, I'm sure you could grow your own citrus trees. But it's really cheap already.

Ya, citric makes things sour. You can use it to coat gummies to make them sour gummies. But what's even better is to just use flavored Kool-Aid, because it's basically flavored citric acid, and mix in some sugar.

And I was just teasing you. I love reading your posts.
Screenshot_20211209-145126.png
This stuff is Citric Acid (beta-Hydroxytricarballylic) and some Molasses. Little dab if this stuff will drop your pH considerably in a 5 gallon bucket. It's what I'm using at the moment to pH down my tap water
Limited-time deal: Safer Gro SG9920QT Ph Down Lowers Water https://www.amazon.com/dp/B00U4YTU0S/ref=cm_sw_r_apan_glt_fabc_dl_55WNX8256ACYQWE7292E?_encoding=UTF8&psc=1
 

PadawanWarrior

Well-Known Member

kratos015

Well-Known Member
@PadawanWarrior beat me to it lol
@kratos015 had been a godsend for me and my Ca issues. Have been following his(your) advice for over a year now, see these same Ca-related issues playing out to a ‘t’ in my grow as well, and much the same, it took me a while to figure that out, far less time than it would have taken however had it not been for kratos’ advice.

I think a really key piece here is that kratos pointed out above that the excess CaCO3 can cause both antagonism of Mg, K and P, as well as pH issues and that both of those issues, while related to CaCO3 content in the soil, can be mutual exclusive from each other in they way they affect the soil biology.

My well water is about 240ppm and right around a pH of 8, I have yet to get an analysis done (which no doubt will be tell tale and insightful), but I know it contains a good amount of CaCO3 given the scaling I see in my pots and on my faucets, etc. I also ran through the peat and pH tests suggested by kratos to see if my water will act as a buffer and it does not, yet I still deal with the issues we are discussing here. This caused a dissonance for me and had me doubting whether it was in fact my water (and it’s Ca content) that was causing the issues. I purchased a quality soil pH pen and found my soil pH to be above 7.5; I then presumed that Ca was responsible for the high pH in and of itself, and began to drop pH of my water with citric acid to around 5.8 with each watering. I did see the soil pH start to get into a range I wanted (between 6.5 and 7), I was happy with this but it didn’t solve the issues/deficiencies that I was dealing with. So back to the drawing board - this is what brought me back to re-reading what kratos had to say about the topic, and then it dawned on me that I wasn’t dealing with a ‘lock out’ (which really only describes a low-pH situation where nutrients can’t be absorbed) but rather I was experiencing significant antagonistic effects of a build-up of CaCO3, so I spent time with the Mulder chart - sure enough it was clear pretty quickly that the excess CaCO3 is likely my culprit due to its antagonizing effect on Mg, K and P, and that it was not simply a ‘pH issue’ in my soil. So my water, while it does not contain enough CaCO3 to act as a buffer, was still giving me CaCO3 issues after it was allowed to build up in my pots.

I should point out that over a year ago, thanks to advice from kratos, I limited my Ca inputs in my soil build - arguably I should have left them out completely. I have no issues during veg, but the two cycles I have ran in this soil have both shown the same Ca-related deficiencies in about week 2 of flower, getting progressively worse curing the cycle.

Now with all this being said, the true test will be how my next run goes as I apply my hypothesis above. I’m planning on flushing my pots, then using RO water for whole next run, I’d love to see a true Ca deficiency lol.

Hardly anyone takes the time to write such detailed responses based on both experience and education, but kratos is THE exception - Id surely be as lost as I was over a year ago without his help and insight. A true expert on the topic!
Dude, you wrote this in such a concise and simple manner. I need to learn from you. Your explanation is brilliant.

Give Langbeinite a try some time, experiment with it, and see how it works for you. I think you'll be surprised.

Like you've said, the excess CaCO3 does in fact have an antagonizing effect on Mg, K, and P. Even worse than this, if one is growing outdoors in the same dry and arid climates that water/dirt with CaCO3 is found in, then Mg and K will literally be leeched from your soil.

Interestingly enough, Langbeinite has Mg and K in it. Furthermore, not only does it have sulfur, but in sulfate form (SO4) which allows it to dissipate CaCO3, as well as other salts. The study (I believe I linked in a prior post?) pointed out how Gypsum is used to leech salts from soils. It pointed out how seemingly counter productive it is to pour more Ca in the form of Gypsum, however, the Gypusm (Calcium Sulfate, specifically) actually removes salts from one's soil.

When one hears the word "salt", one's first thought is "table salt" right? But "salt" isn't just sodium. Take Epsom Salts, for instance. Or the CaCO3 salts we're all having such a productive conversation on.

So, despite the fact Gypsum has Calcium in it, more importantly than that it has Sulfate in it. I have zero scientific basis to back this up, other than my own personal experiences and anecdotes. That said, I am quickly discovering that Sulfates are a crucial part of the living soil process.

Think of a forest fire, and how prolific the growth is after a forest fire. What is the result of fire burning things? Sulfur. Sulfates more specifically, if I'm not mistaken? Sulfur has also been proven to play a direct role in terpene development.

Point being, Langbeinite provides the same "salt leeching" properties that Gypsum does, while simultaneously providing Magnesium and Potassium.

More interestingly, the article I linked in my earlier post address the 0-0-22 NPK of Langbeinite. It claimed that the study found that the soil with Langbeinite in it, had the same K content that the other soils that had no Langbeinite. The study then speculated that the plants, or perhaps the soil itself, was in fact making use of that "excess" K.

Just food for thought, and bravo again on the explanation. As brilliant as it was concise!
 

kratos015

Well-Known Member
Oh ya, I'm sure you could grow your own citrus trees. But it's really cheap already.

Ya, citric makes things sour. You can use it to coat gummies to make them sour gummies. But what's even better is to just use flavored Kool-Aid, because it's basically flavored citric acid, and mix in some sugar.

And I was just teasing you. I love reading your posts.
Unfortunately, my car isn't reliable enough to drive me out to Phoenix. Only place I can buy a citrus tree from. Apparently, it is illegal to import citrus trees to California and Arizona due to specific beetles that can be found on them. That's the reason the border on Cali/AZ exists apparently, not for drug trafficking, but to make sure no one is smuggling citrus trees. I shit you not.

What a world, I can drive weed through the border legally now, but not a citrus tree. Wild.

That's why I asked about it being used to make things sour, I've often seen "citric acid" used as an ingredient for a wide variety of culinary dishes. I think I've even seen it in many of those dank ass BBQ citrus rubs.

Shit, now I'm going to just say fuck it, and rent a U-haul when I get my taxes, drive it to AZ, and load up on lemon and orange trees!

With that in mind, if one did have a citrus tree, then I wonder what the effects of leaving some oranges and/or lemons in your soil would be? When the lemons/oranges decompose, you'd think they'd release the citric acid into the soil itself, no? I'm going to have to look up if anyone has done a study on that. Very interesting that we're often recommended not to feed citrus to worm bins, because of their acidity.


Between Kratos, other informative threads like this one, and my own research/experience, I am coming into the mindset where I plan to not amend my soil with any mineral/nutrient inputs.

In building my own vermicompost (technically a big pile of soil) with native regolith, leaf mold, grass clippings, kitchen vegetable waste, and garden waste, the only items I will be adding to my next soil mix with this base are mycos, aeration, and something inert to cut the strength of said compost. I am very curious to know how that will work for cannabis, and plan to mix this soil up soon so I can start testing!
Why I emphasize my "experience". It took me over a decade to learn to have that mindset, so it truly does my heart joy to know that people are learning what took me 10 years in just a single year.

That compost you just described sounds like a wet dream, your plants will surely thank you. Why I started my journal in the first place. I know very little about growing produce, and I'm learning so much. That said? The same soil that has given me such tremendous success for cannabis, I theorized, why wouldn't it give me the same success for other plants?

And, like cannabis, certain tomatoes/vegetable strains do great in my climate, and other strains hate it. Some tomatoes love it here, others will die immediately. Just like cannabis, or greens, or brassicas, or people.
 

PadawanWarrior

Well-Known Member
Unfortunately, my car isn't reliable enough to drive me out to Phoenix. Only place I can buy a citrus tree from. Apparently, it is illegal to import citrus trees to California and Arizona due to specific beetles that can be found on them. That's the reason the border on Cali/AZ exists apparently, not for drug trafficking, but to make sure no one is smuggling citrus trees. I shit you not.

What a world, I can drive weed through the border legally now, but not a citrus tree. Wild.

That's why I asked about it being used to make things sour, I've often seen "citric acid" used as an ingredient for a wide variety of culinary dishes. I think I've even seen it in many of those dank ass BBQ citrus rubs.

Shit, now I'm going to just say fuck it, and rent a U-haul when I get my taxes, drive it to AZ, and load up on lemon and orange trees!

With that in mind, if one did have a citrus tree, then I wonder what the effects of leaving some oranges and/or lemons in your soil would be? When the lemons/oranges decompose, you'd think they'd release the citric acid into the soil itself, no? I'm going to have to look up if anyone has done a study on that. Very interesting that we're often recommended not to feed citrus to worm bins, because of their acidity.




Why I emphasize my "experience". It took me over a decade to learn to have that mindset, so it truly does my heart joy to know that people are learning what took me 10 years in just a single year.

That compost you just described sounds like a wet dream, your plants will surely thank you. Why I started my journal in the first place. I know very little about growing produce, and I'm learning so much. That said? The same soil that has given me such tremendous success for cannabis, I theorized, why wouldn't it give me the same success for other plants?

And, like cannabis, certain tomatoes/vegetable strains do great in my climate, and other strains hate it. Some tomatoes love it here, others will die immediately. Just like cannabis, or greens, or brassicas, or people.
The new threat is the Mountain Pine Beetle. But they're checking for other critters that travel through food too. Fuck I'm starting to itch already. Anyways I lived in Truckee and went through a checkmate point everytime I drove up I-80 to Boreal or SugerBowl. They'd always ask if we had any fruits or vegetables. Never asked if we had an arsenal of weapons or a kilo of coke.

 

Bukvičák

Well-Known Member
@PadawanWarrior beat me to it lol
@kratos015 had been a godsend for me and my Ca issues. Have been following his(your) advice for over a year now, see these same Ca-related issues playing out to a ‘t’ in my grow as well, and much the same, it took me a while to figure that out, far less time than it would have taken however had it not been for kratos’ advice.

I think a really key piece here is that kratos pointed out above that the excess CaCO3 can cause both antagonism of Mg, K and P, as well as pH issues and that both of those issues, while related to CaCO3 content in the soil, can be mutual exclusive from each other in they way they affect the soil biology.

My well water is about 240ppm and right around a pH of 8, I have yet to get an analysis done (which no doubt will be tell tale and insightful), but I know it contains a good amount of CaCO3 given the scaling I see in my pots and on my faucets, etc. I also ran through the peat and pH tests suggested by kratos to see if my water will act as a buffer and it does not, yet I still deal with the issues we are discussing here. This caused a dissonance for me and had me doubting whether it was in fact my water (and it’s Ca content) that was causing the issues. I purchased a quality soil pH pen and found my soil pH to be above 7.5; I then presumed that Ca was responsible for the high pH in and of itself, and began to drop pH of my water with citric acid to around 5.8 with each watering. I did see the soil pH start to get into a range I wanted (between 6.5 and 7), I was happy with this but it didn’t solve the issues/deficiencies that I was dealing with. So back to the drawing board - this is what brought me back to re-reading what kratos had to say about the topic, and then it dawned on me that I wasn’t dealing with a ‘lock out’ (which really only describes a low-pH situation where nutrients can’t be absorbed) but rather I was experiencing significant antagonistic effects of a build-up of CaCO3, so I spent time with the Mulder chart - sure enough it was clear pretty quickly that the excess CaCO3 is likely my culprit due to its antagonizing effect on Mg, K and P, and that it was not simply a ‘pH issue’ in my soil. So my water, while it does not contain enough CaCO3 to act as a buffer, was still giving me CaCO3 issues after it was allowed to build up in my pots.

I should point out that over a year ago, thanks to advice from kratos, I limited my Ca inputs in my soil build - arguably I should have left them out completely. I have no issues during veg, but the two cycles I have ran in this soil have both shown the same Ca-related deficiencies in about week 2 of flower, getting progressively worse curing the cycle.

Now with all this being said, the true test will be how my next run goes as I apply my hypothesis above. I’m planning on flushing my pots, then using RO water for whole next run, I’d love to see a true Ca deficiency lol.

Hardly anyone takes the time to write such detailed responses based on both experience and education, but kratos is THE exception - Id surely be as lost as I was over a year ago without his help and insight. A true expert on the topic!
What kind of soil and what kind ph meter?
 

hotrodharley

Well-Known Member
Thanks, I'm learning a lot here. I did get an RO unit but am hesitant in using it at the moment. I might just play out this grow just using the tap water. And as mentioned above (I think I mentioned it here, on so many threads right now), dropping the lights 25% has done wonders to the ladies. I'm still in disbelief. They're praying and have wonderful color like never before.
If you run tapwater straight into an RO unit the chlorine will destroy the semipermeable membrane.
 

Week4@inCharge

Well-Known Member
If you run tapwater straight into an RO unit the chlorine will destroy the semipermeable membrane.
probably, the Stealth 150 unit I have has a charcoal chamber before the water gets to the membrane. And as luck would have it, my very first attempt at using it, the hose adapter (cheap hose adapter) that came with the unit stripped. So yeah, nice unit, cheap adapter equals....can't use that dam peice of shit. So have to wait a bit for the replacement to come in.
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