Less absorbance does not mean the photons are less usable. It just means there's a lower probability they will be absorbed. But if it's not absorbed in one place, it will be absorbed somewhere else... the lower part of the plant!
YES...
Plants have been involved for some ..million ..of years under the Sun's light.
The two basic
photosynthetic pigments ( ChA & ChB ) of
higher plants ,are adapted to the Sun's light,regarding
their
ABSORPTANCE.
But there are also OTHER photosynthetic mechanisms / substances. (Some not even pigments ,like the
LIGHT HARVESTING PROTEIN COMPLEXES I & II ).
Overall ,higher plants all they want is to absorb as much photons as possible.
(Especially the light -needy plants ,those that they produce complex /massive flowers and large fruits.
More energy absorbed = more biomass produced.)
Still ,that does not mean that the absorbed photons are equally able to drive PS .
Blue photons (the most abundant,even in cloudy weather / winter ) ,are the least efficient driving PS.
Actually ,due to their high energy they can harm the plant tissue & DNA .
(Thus the PHOTO-QUENCHING PIGMENTS like the CAROTENOIDS ,
that absorb mostly blue photons and turn the excess energy into HEAT and/or FR light )
Still ,the answer to the enigmatic question of why plants are reflecting some green and not being totally black ,can probably be found in the actual mineral /element that is used to turn photons into electrons ,at the two basic photosynthetic pigments.
"
Chlorophyll is a chlorin pigment, which is structurally similar to and produced through the same metabolic pathway as other porphyrin pigments such as heme. At the center of the chlorin ring is a magnesium ion. "
http://en.wikipedia.org/wiki/Chlorophyll
Magnesium ( Mg ) is
quite abundant in ( or " at " ? ) Earth's surface and
quite easy to be " light -excited " .
The best available choice for the plants ( At planet Earth ,at least ...).
But ,check the Magnesium's "emission" spectrum ,as an element .
http://en.wikipedia.org/wiki/Emission_spectrum
http://student.fizika.org/~nnctc/spectra/Mg_1024.htm
http://www.umop.net/spctelem.htm
Magnesium reflects / emits green photons when excited .
Plants ,simply,could not "find" a better option ,than Mg.
Still,they have evolved other photosynthetic mechanisms / substances./ accessory PS pigments ,
in order to "compensate" for that "weakness" of Mg .
Let alone ,that "green window " or the "shade avoidance ",
"mechanisms" that turn that "weakness" of Mg ,into a "survival / thriving " aiding aspect ....
Cheers.