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Apologies, I did not read your original statement correctly and made assumptions, forgetting to take into account the fact that the Armor Si™ is in fact only 10% SiO₂ and that the 264 ppm value refers to the 1ml of Armor Si™ and not SiO₂ or Si. To finish though, using an online molar mass...

Your calculation is actually this: 1 ml ÷ 3785.41 ml (1 US gal) x 100 = 0.0264% 0.0264% x 10,000 = 264 ppm 10x more than you think. Also, when you say "elemental", SiO₂ is actually a compound of which Si makes up 46.75% of SiO₂. The instructions on the label state 1 tsp per gal = 1 ml per...