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Well since the mold stuff was only on one bud we just cut it off. Any idea about the black stuff on the stem?

Hi guys, First time ever growing, this is an outdoor setup. The weed is ready for harvest from what I gather. I have found these black lava spots on the stems, trunk and in some buds. Can you tell me is it still safe to smoke? Also I found ONLY on one bud a white moss like structure. Can...